The Synthesis, Resolution and Configuration of Beta-hydroxyvaline

Synthesis, resolution, and configuration of alpha-hydroxyvalin

Optical Resolution and Configuration of Trans-2,3-epoxybutyric Acid

Optical resolution of epoxy derivative of butyric acid with brucine and configuration determination by treatment with ammoni

Spin solid phases of spin 1 and spin 3/2 antiferromagnets on a cubic lattice

We study spin S=1 and S=3/2 Heisenberg antiferromagnets on a cubic lattice focusing on spin solid states. Using Schwinger boson formulation for spins, we start in a U(1) spin liquid phase proximate to Neel phase and explore possible confining paramagnetic phases as we transition away from the spin liquid by the process of monopole condensation. Electromagnetic duality is used to rewrite the theory in terms of monopoles. For spin 1 we find several candidate phases of which the most natural one is a phase with spins organized into parallel Haldane chains. For spin 3/2 we find that the most natural phase has spins organized into parallel ladders. As a by-product, we also write a Landau theory of the ordering in two special classical frustrated XY models on the cubic lattice, one of which is the fully frustrated XY model. In a particular limit our approach maps to a dimer model with 2S dimers coming out of every site, and we find the same spin solid phases in this regime as well.Comment: 15 pages, 8 figure

Gravitational Radiation from a Naked Singularity -- Odd-Parity Perturbation --

It has been suggested that a naked singularity may be a good candidate for a strong gravitational wave burster. The naked singularity occurs in the generic collapse of an inhomogeneous dust ball. We study odd-parity mode of gravitational waves from a naked singularity of the Lema\^{\i}tre-Tolman-Bondi space-time. The wave equation for gravitational waves are solved by numerical integration using the single null coordinate. The result is that the naked singularity is not a strong source of the odd-parity gravitational radiation although the metric perturbation grows in the central region. Therefore, the Cauchy horizon in this space-time would be marginally stable against odd-parity perturbations.Comment: 14 pages, 7 figures, to be published in Prog. Theor. Phys. Final version, with minor changes. Reference 13 adde

Nonlinear Pattern Selection in Binary Mixture Convection with Through-Flow

The pattern selection problem in binary-mixture convection in an extended channel with a lateral through-flow is presented. The through-flow breaks left--right parity and changes pattern dynamics dramatically. The problem is studied based on computer simulation of the complete set of hydrodynamic equations (Oberbeck-Boussinesq approximation) in the two-dimensional rectangular channel with aspect ratio $\Gamma = 12$ and convection-suppressing lateral boundary conditions. A wide variety of new dynamical patterns is obtained, discussed and classified.Comment: 9 pages and 2 figure

Gravitational Radiation from a Naked Singularity. II - Even-Parity Perturbation -

A naked singularity occurs in the generic collapse of an inhomogeneous dust ball. We study the even-parity mode of gravitational waves from a naked singularity of the Lema\^{\i}tre-Tolman-Bondi spacetime. The wave equations for gravitational waves are solved by numerical integration using the single null coordinate. The result implies that the metric perturbation grows when it approaches the Cauchy horizon and diverges there, although the naked singularity is not a strong source of even-parity gravitational radiation. Therefore, the Cauchy horizon in this spacetime should be unstable with respect to linear even-parity perturbations.Comment: 16 pages, 5 figures, errors and typos corrected, final versio

Development of Improved Rhenium Coatings for Fluorine Engine Thrust Chambers

Coating trials were undertaken to evaluate the application of rhenium to carbon-carbon composite sheet by plasma spraying. Optimum spray parameters and coating thickness were identified for production of coatings free from continuous defects and with adequate adherence to the substrate. A tungsten underlayer was not beneficial and possibly detracted from coating integrity. Stress calculations indicated that the proposed operating cycle of the rocket engine would not cause spalling of the rhenium coating. Calculations indicated that permeation of gases through the coating would not be significant during the expected life of the thrust chamber. The feasibility of applying rhenium coatings by laser melting was also studied. Poor wetting of the composite surface by the liquid rhenium precluded production of uniform coatings. Borate/carborate fluxes did not improve wetting characteristics

N\'eel and Spin-Peierls ground states of two-dimensional SU(N) quantum antiferromagnets

The two-dimensional SU(N) quantum antiferromagnet, a generalization of the quantum Heisenberg model, is investigated by quantum Monte Carlo simulations. The ground state for $N\le 4$ is found to be of the N\'eel type with broken SU(N) symmetry, whereas it is of the Spin-Peierls type for $N\ge 5$ with broken lattice translational invariance. No intermediate spin-liquid phase was observed in contrast to previous numerical simulations on smaller lattices [Santoro et al., Phys. Rev. Lett. {\bf 83} 3065 (1999)].Comment: 4 pages, 4 figure

Physical Processes in Naked Singularity Formation

Gravitational collapse is one of the most fruitful subjects in gravitational physics. It is well known that singularity formation is inevitable in complete gravitational collapse. It was conjectured that such a singularity should be hidden by horizons if it is formed from generic initial data with physically reasonable matter fields. Many possible counterexamples to this conjecture have been proposed over the past three decades, although none of them has proved to be sufficiently generic. In these examples, there appears a singularity that is not hidden by horizons. This singularity is called a `naked singularity.' The appearance of a naked singularity represents the formation of an observable high-curvature, strong-gravity region. In this paper we review examples of naked singularity formation and recent progress in research of observable physical processes - gravitational radiation and quantum particle creation - from a forming naked singularity.Comment: 76 pages, 25 figure file